As Dr. Motasem said that COD and BOD could be used as paramters for efficiency of electrocoagulation of waste water also you can meause TSS, turbidity and volatile suspended solids (VSS).
For different pollutants in wastewater, the COD parameter can be used to find the current efficiency of electrocoagulation process using the following eq.:
CE(%)=(CODo-CODt) * F * V *100/ 8 I t
Where: CODo is the initial chemical oxygen demand and CODt is the chemical oxygen demand at time t
Landfill leachate contains different kind of pollutants that can be measured/quantify in terms of COD, BOD, TOC,. As Professor Ghanim A. N., Answered in details and you can also look this articles.