Hussein Ali Kadhim Kyhoiesh, First, S, H, and G are not kinetic parameters, but thermodynamic state functions. Secondly, it is best to try to estimate the kinetic parameters A and E for the subsequent stages of thermal decomposition on the basis of the DTG curve, after its deconvolution. I would also avoid methods that result in the so-called activation energy as a function of temperature. The software is usually supplied with the instrument.