Dear Manoj Jangid,
start[1,4] with the refs[2,3]; then, you might follow some of their refs[1] and citations[2-4], for a more deep learning, also.
1. Galvanostatic Intermittent Titration Technique http://www.ecochemie.nl/download/Applicationnotes/Autolab_Application_Note_BAT03.pdf
2. Analysis of the Galvanostatic Intermittent Titration Technique (GITT) as applied to a lithium-ion porous electrode http://www.sciencedirect.com/science/article/pii/S0378775308018387
3. Spurious chemical diffusion coefficients of Li+ in electrode materials evaluated with GITT http://www.sciencedirect.com/science/article/pii/S0013468604011600
4. Determination of the kinetic parameters of mixed-conducting electrodes and application to the system lithium antimonide, Weppner, W.; Huggins, R. A.; Journal of the Electrochemical Society (1977), 124(10), 1569-78 CODEN: JESOAN; ISSN: 0013-4651. English.
Dear Manoj Jangid,
start[1,4] with the refs[2,3]; then, you might follow some of their refs[1] and citations[2-4], for a more deep learning, also.
1. Galvanostatic Intermittent Titration Technique http://www.ecochemie.nl/download/Applicationnotes/Autolab_Application_Note_BAT03.pdf
2. Analysis of the Galvanostatic Intermittent Titration Technique (GITT) as applied to a lithium-ion porous electrode http://www.sciencedirect.com/science/article/pii/S0378775308018387
3. Spurious chemical diffusion coefficients of Li+ in electrode materials evaluated with GITT http://www.sciencedirect.com/science/article/pii/S0013468604011600
4. Determination of the kinetic parameters of mixed-conducting electrodes and application to the system lithium antimonide, Weppner, W.; Huggins, R. A.; Journal of the Electrochemical Society (1977), 124(10), 1569-78 CODEN: JESOAN; ISSN: 0013-4651. English.
Thank you Prof. Samaras for sharing the references. Hope these will be sufficient for the solution of my problem.
Regards.
Manoj Jangid
Dear Manoj Jangid and Prof. Samaras
How about your calculation? Actually I got GITT curves look very nice, but when I calculate the diffusion coefficient, there is change depending on SOC, so how I can choose the value, just take average or choose at some specific points? Thank you very much.
Anh Bui Dinh :
The diffusion coefficient D(SOC) depends (firmly[1], and) on the SOC, also.
1. Determination of the kinetic parameters of mixed-conducting electrodes and application to the system lithium antimonide, Weppner, W.; Huggins, R. A.; Journal of the Electrochemical Society (1977), 124(10), 1569-78 CODEN: JESOAN; ISSN: 0013-4651. English.
I want add few items else (mostly about use of GITT):
- P.P. Prosini, M. Lisi, D. Zane, M. Pasquali. Determination of the chemical diffusion coefficient of lithium in LiFePO4.
Solid State Ionics, V. 148, I. 1, May 2002, P. 45-51.
- M.S. Mattsson. Li insertion into WO3: introduction of a new electrochemical analysis method and comparison with impedance spectroscopy and the galvanostatic intermittent titration technique. Solid State Ionics 131, 2000, 261-273
- J. Deng, C.Y. Chung, X. Han, Y. Zhong, Zh. Wang, H. Zhou. Electrochemical Properties of LiNi0.50Co0.25Mn0.25O2 Thin Film Cathodes Prepared by Pulsed Laser Deposition. Int. J. Electrochem. Sci., (2013) Vol. 8, 1776
- Y.-S. He, Z.-F. Ma, X.-Z. Liao, Y. Jiang, J. Power Sources, 163 (2007) 1053.
- C.L. Liao, Y.H. Lee, K.Z. Fung, J. Alloys Compd., 436 (2007) 303.
- H. Xia, L. Lu and M.O. Lai, Electrochim. Acta, 54 (2009) 5986.
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