I would like to calculate the boiling point for propylene carbonate:acetone and propylene carbonate:ethanol:acetone. May i know what formula can be used for the calculation? Thanks
Dear Lee,
Use one of the Phi-Phi or gamma-Phi approaches. Antoine's equation calculates the vapor pressure of each component. Depending on the operating pressure of your system, use the low pressure VLE equation or the high pressure VLE equation for each component. Finally, use the method of Lewis Sorel to calculate the number of Trays.
You can use also a simulation model like Aspen Plus or Chemcad…
With my best regards
Prof. Bachir ACHOUR
Dear Lee,
We can use an Ebulliometer, a device to accurately measure the boiling point of pure solvents or mixture of solvents.
We can use Joback method. This method is an estimation of normal boiling points from molecular structure.
Simulation is also a tool to calculate boiling point (Himmelblau).
With my best regards!
Dr. Adel OUESLATI
Dear Prof. Bachir ACHOUR ,
thank you so much for the solution. However, may i know what temperature should i set for the calculation? how to make use the tray number to determine the boiling point?
Dear Dr. Adel OUESLATI ,
Thank you so much for the solutions. I will try out the simulation tool.
You may want to check also this related RG discussion: https://www.researchgate.net/post/How_can_I_calculate_the_Boiling_Point_of_Liquid_Mixtures
Attached file is from university of Calgary and is very helpful in boiling point determination of mixture solutions
Dear Lee Wah,
It’s easy to calculate boiling point by formula, △Tb= Kb m
Where m is molality(n/M). Delta in the formula to indicate that you’re calculating a change in the boiling point, not the boiling point itself. You need to add this number to the boiling point of the pure solvent to get the boiling point of the solution. The units of Kb are typically given in degrees Celsius per molality.
A solution typically has a measurably higher boiling point than the pure solvent. Boiling point elevation refers to the tendency of a solvent’s boiling point to increase when an impurity (a solute) is added to it. Boiling point elevations are a result of the attraction between solvent and solute particles in a solution.
Colligative properties such as boiling point elevation depend on only the number of particles in solution. Adding solute particles increases these intermolecular attractions because more particles are around to attract one another. To boil, solvent particles must therefore achieve a greater kinetic energy to overcome this extra attractive force, which translates into a higher boiling point.
Ashish
- Badges
- Science topic
- Similar topics
- Applied Mathematics
- Calculations