in order to get a wavelength-dependent PL, you must increase the wavelength of the exciting light, passing to excitation of PLat the red edge of the absorption spectrum
I would recommend to investigate excitation-emission contour profile if you have highly wavelength-dependent emission profile (PL/PLE). Most fluorescence spectrophotometer let you sweep a range of excitation wavelength while recording excitation-specific emission profile.
You can check out the paper linked below for contour profile.
Article Conformation-mediated Forster resonance energy transfer (FRE...