What are the time scales for rotational reorientation, rotational diffusion times and correlate to solvent reorganization in condensed phase femtosecond pump probe study?
Consider a organic molecule soluble in both polar and nonpolar solvent and assume that it is dissolved in polar solvent (MeOH/EtOH/DMSO/DCM) and in a nonpolar solvent (ChCl3/Toluene,etc). Under this condition how could you correlate between the time scales obtained under Femtosecond pump probe spectroscopy? (Ignore Protic and aprotic solvents)