There are few ways to improve the absorption of electromagnetic waves in metal surface, but before that, you should be very specific for which region of the electromagnetic wave band you are interested.
For example: Metals like Al, Cu, Ag shows very good absorptivity in the Ultra violet region. whereas, in infrared red region the absorptivity is very less (~ 2-5%).
Generally there will be few ways of improving the absorption of electromagnetic waves from U.V to far infrared region.
(i) increase the temperature of the metal substrate.
(ii) increase the roughness of metal surface.
(iii) put a thin coating of Carbon over the metal surface.