Literature shows both host as well as emissive fluorophores contains D-A-D type or D-A type of structure in its frame work, so how to decide whether it can be used as a host or emissive layer in OLED.
You can find detail of your question in this this articles which completely covers all aspects of TADF.
Methods Appl. Fluoresc. 5 (2017) 012001 Article Photophysics of thermally activated delayed fluorescence molecules
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