Many compounds, most high temperature superconductors for example, were got by solid state reaction. How did researchers design such experiments?
You can see some details in our paper
https://www.researchgate.net/publication/249322517_Solid-State_Synthesis_of_Co-Sm%28110%29_Epitaxial_Films_with_Large_Magnetocrystalline_Anisotropy?ev=prf_pub
Article Solid-State Synthesis of Co-Sm(110) Epitaxial Films with Lar...
Try to find some text books on inorganic chemistry, there you will probably find suitable routes and "cook-book" like recipes. It will mostly depend on the materials that you are aiming. Good luck, Dirk
You can find the "A. R. West "Solid State Chemistry and its Applications" Chapter 2 –
Preparative Methods", in that they have given the process of solid state reaction.
good luck.......................
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