Request to drop these values while giving functional groups (S)-4–Iodonicotine ; IR (thin film) 2966, 2937, 2830, 2779, 1559, 1537, 1453, 1394, 1453, 1394, 1354, 1218, 1057, 850 cm-1
Consulting FTIR table is your first step, however, when it comes to inorganic molecule you need consider a few parameters interpret specially the fingerprint regions.Solvent, humudity are a few the exaples. From the FTIR you stated, it is very straight forward to interpret the spectra.For example, 2966, 2937 -CH3 and CH2 anti & sym of CH str.
850 C-Cl str. and 1559 is probably due to the ring str. etc
And on the other hand we have : (S)-2-chloro-5-(1-methyl-pyrrolidin-2-yl)pyridine ( (S)-2-chloronicotine ) ;IR (neat) 2969, 2943,2809, 2779, 1584, 1573, 1567, 1454, 1104 cm-1.
Under an atmosphere of argon, 2,2,6,6-tetramethylpiperidine (370 μL, 2.2 mmol, 1.1 equiv) in dry THF (5 mL) was cooled to – 78 °C and treated with n-butyllithium (2.0 mmol, 1.0 equiv). The solution was stirred at 0 °C for 30 min, then the mixture was cooled to – 78 °C and treated with di-t-butylzinc (2.4 mmol, 1.2 equiv), prepared from zinc chloride (4.8 mL, 0.5 M in THF, 2.4 mmol) and t-butyllithium (4.8 mmol, 2.4 equiv). The mixture was then stirred at room temperature for 1 h. (S)-Nicotine (320 μL, 2.0 mmol, 1.0 equiv) was added dropwise at room temperature, and the mixture was stirred overnight. Iodine (2.03 g, 8.0 mmol, 4.0 equiv) was added to the reaction mixture. The flask was wrapped by aluminum foil to protect the reaction from light. The reaction was quenched with 1.0 mL of a saturated aqueous solution of sodium bicarbonate. The cold aqueous layer was extracted with methylene chloride, and the combined organic layers were dried over magnesium sulfate. The solvent was removed by evaporation to afford a yellow oil. The product was purified by radial PLC (silica gel, 1% TEA/hexanes). (S)-2-Iodonicotine was obtained in a 19 % yield (107 mg) as a light yellow oil, and (S)-4-Iodonicotine was obtained in a 24 % yield (139 mg) as a white solid .