In general bi tosyl group substituted phenylene diamine only is easy, but how is it possible to get a monosubstituted compound?
Hasan Kucukbay
You can choose the nitroanilines as a starting compond, after tosylated the amino group you can use reduction for the nitro group with ETOH/Zn.
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Mohyeddin Assali
You can use 1 eq. Of tosyl group and 1 eq of the phenylene diamine, you will get mixture of the disubstituted and monosubstituted which can be easily separated by column chromatography
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