Is this possible to synthesize a monosubstitution in Phenylenediamine?

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Elena Yu. Ladilina

CF3C(O)OMe + H2N-R-NH2, molar ratio due 1 : 1, without of reagents excess, amine add to the ether slowly by Intensive stirring.

Kyle A. Grice

Mono-BOC protection is also known for aryl and alkyl diamines

http://www.tandfonline.com/doi/abs/10.1081/SCC-100106036#.UnzvL_k4Wb8

http://www.tandfonline.com/doi/abs/10.1080/00397910601131403#.UnzvJ_k4Wb8