1. Logic of the Second Law of Thermodynamics: Subjectivism, Logical Jump, Interdisciplinary Argumentation.
2. New thermodynamics pursues universality, two theoretical cornerstones:
2.1 Boltzmann formula: ro=A*exp(-Mgh/RT) - Isotope centrifugal separation experiments show that it is suitable for gases and liquids.
2.2. Hydrostatic equilibrium: applicable to gases and liquids.
3. The second and third sonic virial coefficients of R143a derived from the new thermodynamics are in agreement with the experimental results.
3.1. The third velocity Virial coefficient derived is in agreement with the experimental data, which shows that the theory is still correct when the critical density is reached.
4. See Appendix Pictures and Documents for details.
You have to calculate the related ratios of elements by Excel. Then you can use Excel, Origin, or some other graph software to draw the Gibbs diagram.
However, the Gibbs diagram represents some of the key processes controlling surface water chemistry, and is unlikely to represent key processes controlling the chemistry of most groundwater systems (Marandi and Shand, 2018).
Ref: Marandi and Shand, 2018. Groundwater chemistry and the Gibbs Diagram. Applied Geochemistry, 97: 209-212.