On your SEM images, if the pores are visible, then either you can ask the SEM operator to mark the lengths of the pores or you yourself can take the scale given at the bottom of the image as standard, and mark yourself.
One simple method is by using ImageJ Software, it is free and user-friendly. It can determine pore size and distribution, surface porosity and even the roughness (units are not expressed in nm) with a 3D mapping of the SEM image, among other uses.
There are several articles in membrane science that used this software for different purposes.
I recommend two articles that will be very helpful for basic ImageJ quick learning:
1. Rishi et al., Particle Size and Shape Analysis using Imagej with Customized Tools for Segmentation of Particles, International Journal of Computer Science and Communication Engineering, 2015.
2. Rishi et al., Particle Size and Shape Analysis using Imagej with Customized Tools for Segmentation of Particles, International Journal of Engineering Research & Technology, 2015.
If you want further details and other articles please do not hesitate to contact me.