I am not aware about the applications of such double perovskites in the field of photocatalysis.
However, this can be a very good material as a potential replacement of lead based perovskites due having ns2 electron. Carrier life time is high. The environmental stability of the materials are very good.
Unfortunately the PCE has not been excelled yet due to large band gap and poor charge transport. Once these issues are solved it may arise as a very good solar cell material.