I want to measure ZT of a piece of Bi2Te3 pellet, using the Harman-technique.

What geometry should I use,

what magnitude of current(density),

2-probe or 4-probe, and

how should I anchor thermally the ends of the sample?

I am trying with 1cm diameter cylinders, few mm tall,

and also with 2*2mm2 long bars, 1cm long.

I have tried to place the cylinder between massive metal pieces (thermally anchored): this seems to yield reasonable ZT, but is excessively slow,

and also leaving the bar dangling in vacuum: this is fast but does not seem to give a decent extra "Peltier-voltage" on top of the Ohmic voltage.

Contacts were made my electroplated Nickel, and soldered brass plates.

Many thanks for any practical advice.

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