my reaction is an assymetric 1,3-dipolar cycloaddition. I think that the main product that was determined by X-ray should have the ts with the loest energy.
contrary to my hypothesis, the data deriving from gaussian, reveals that my main product has higher energy than tow of ts's. now, how can I solve this paradox?
thank's for your considration.
Fernando Vallejos-Burgos
Is not only TS (kinetic distribution), also final energy of the competing products is important (equilibrium distribution).
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