If electron temperature and electron excitation temperatures in plasmas are different, then, is there any case they will be equal or always remain unequal?
Please read the following publications dealing with the subject in detail:
1. Pure Appl. Chem., (2013) 85(12), 2231–2248
'Departure from local thermal equilibrium during
ICP-AES and FAES: Characterization in terms of
collisional radiative recombination activation energy'
Mark F. Zaranyikam, Courtie Mahamadi
2. Spectrochim. Acta, Part B 37, 987 (1982)
'Evaluation eines Elektronendiffusionsmodelles zur Berechnung
von nicht Gleichgewichts-Elektronenkonzentrationen im Induktiv
gekoppelten Argonplasma fiir die spektrochemische Analyse'
F. Aeschbach
In plasmas the electron temperature is always much different from the temperature based on the mean kinetic energy of atoms , ions and small molecules.
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