The relationship between the thermal and electrical conductivities in semiconductors is quite lawful, the law of Wiedemann-Franz has only a few exceptions and deviations. But this law is about semiconductors as materials. So the question I needed answered is whether this law also persists when you start fiddling with the electrical conductivity of the semiconductors by making a junction, like a diode, bi-polar transistor or MOSFET. I would say yes, but (from my point of view) material science is sometimes dangerously unintuitive.
As for an example, consider the following case of the schematic in attachment. Is the thermal conductive path between the battery cell and the resistor in which heat is created dependent on whether the MOSFET is on/off or it's duty cycle?
I know electronics, but I am not a materials expert. I don't find any publications regarding the matter. Any answers, publications or ideas on how to set-up an experiment (you should take into account the heat losses when changing between on-and off) are welcome.