I've been trying to do my calculations related to optimization of excited state of ion CH5+ using method TD-DFT with M06-2X and aug-cc--pVTZ. My input file is as shown below:

%nproclinda=1

%nprocshared=32

%mem=6GB

%oldchk=step_2.chk

%chk=step_4

#P m062x/aug-cc-pVTZ TD=(Read,NStates=6,Root=1,MaxCycle=700) Geom=Modify Guess=Read Opt Int = UltraFine

CH5+: excited state opt

1 1

Unfortunetaly I get a following message:

"Error termination request processed by link 9999."

After optimiaztion the structure does not have any imaginary frequencies.

Could You please help me solve that issue?

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