It depends on the context. exploring for gold with hydro geochemistry, particularly for surface waters, with ground water one would need 1ppt min LDL gold, about 10ppt for silver and 100 ppt for arsenic. Even then one would normalize erosion/dissolution with silicon content. The convenient high res ICP-MS technology is improving, yet older Nuclear activation technology is still best, though utility marginal at best. Yes, it is a vector to improvement. Even in our own in house efforts with Atomic striping voltammetry (ASV, PDV6000+ square wave unit), we aim to use gel chromatography to resolve organic interference, enhance signal with lanthanum ligated gels. Otherwise our field instrument can optimally detect 0.5 ppb As, Cu, only sufficient for near surface blind mineralisation. You can't take an MS unit in the field! So in conclusion, for us at least, it is a driver for improved technology: reconcentration and handling interference, whilst ASV technology, and others now such a biological metal(oid) sensors improve for field works and low cost analysis.