If you have identified the liquidus peak, the liquidus line point should be selected by the linear interpolation between the endothermic peak and the baseline. For convenience, in organic materials, the maximum value of the peak is selected as transition temperature, but in inorganic materials is taken at the beginning of the peak.
More information can be found in the book "DTA and Heat-flux DSC Measurements of Alloy Melting and Freezing".