Hello everyone,
My question is divided into two:
(1) I want to know the difference between vertical Ionization potential and Adiabatic Ionization potential
(2) How do we calculate the Binding energy of ionic metal oxide clusters. Though how to calculate that of neutral clusters is cleared to me but that of ionic cluster is not clear.
Wish anyone can help me with the 2 question above. Thank you in anticipation
The answer for your 1st query
In conclusion, the first member of a vibrational progression, the ion is formed in the zero point vibrational level, v = 0. The corresponding ionization process is said to be the adiabatic ionization transition, so-called because the ion has no excess vibrational energy. The most intense vibrational component is said to be due to a vertical ionization, because it most closely corresponds to the vertical transition in a classical picture of the Franck–Condon principle.
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