Synthesis of Silica nanoparticles was done by the Stober method. STF is prepared from this nanoparticles dispersion sample. But not getting a standard STF viscosity profile in Rheometer. Can anyone suggest me?
Shear thickening happens for high filler concentrations and "odd shaped" particles, i.e. particles that have a rough surface that can connect to each other easily.
Therefore, I would suggest you to check the shape of your particles e.g. by SEM and increase the concentration in the STF
Yes, STFs can be prepared from the synthesised silica nanoparticles.
I hope you are refering 'standard STF viscosity profile' to the steep rise in viscosity at a certain value of shear rate. If yes, probably the solid content is lower. With silica and PEG, solid content of about or above 65% shows visible shear thickening.
Other possible solutions, if the STF is properly prepared.
# Try adjusting the gap between the plates (or cone and plate) of the rheometer.
# Check the temperature of the plates. Too hot a setting may not reveal the expected profile.
# Make sure the STF does not absorb moisture upon storage.
# Use preshear before the actual rheology test.
Otherwise, ensure proper dispersion through optimum sonication.
The above answers will adjust the shear thickening nature of the mixture, but it may be best to check your viscosity test method as well. When the sample thickens a lot and you force it to move still it will tend to fracture from the gap and you get incorrect measurements. An alternative way is to run a stress ramp test instead of a shear rate ramp test, as this should keep the sample in situ.
Also Prof. Abhijit Majumdar, Department of Textile Technology, IIT Delhi, has a number of published articles on this. Since you are from the same Institute, maybe you can refer to his work.