There is a case study for the city of Liverpool in the UK attached for information Dagani. More useful information can be obtained from http://www.gdrc.org/uem/footprints/
Definitely, you can apply WFA for a city. recently we have concluded the WFA study fro Delhi-NCR at NIH including all three major sectors (i.e. Agri. Domestic and Industrial) for Blue, green and grey component. We have also considered the floating population as well as virtual water import and exports in form of commodities.