Yes it is because of increased temperature at the point of contact and it can be explained in this way:
The heat which is produced due to the flow of current within an electric wire, is expressed in Joules. Now the mathematical representation or explanation of Joule’s law is given in the following manner.
1) The amount of heat produced in current conducting wire, is proportional to the square of the amount of current that is flowing through the circuit, when the electrical resistance of the wire and the time of current flow is constant.
i.e. H = i2 (When R & t are constant)
2) The amount of heat produced is proportional to the electrical resistance of the wire when the current in the circuit and the time of current flow is constant.
i.e. H = R (when i & t are constant)
3) Heat generated due to the flow of current is proportional to the time of current flow, when the resistance and amount of current flow is constant.
In the photo case, the guy was stealing a high voltage wire, then he fall and the cable tangle around his thigh, wrist and neck, his right hand was amputated.
I´m agree with Dr. Hayman that current travels along the major vessels because the low blood electric resistance, that is the way reaches the central nervous system and the heart and cause death because of respiratory and circulatory failure.
But in the cases we are discussing here (post mortem amputations) the mechanism is because of increased temperature at the point of contact.
I have seen "amputation" in cases of electrocution especially in the accidents that happen on the overhead power line.
Dr. Herbstein gave you the explanation of how this phenomenon works, nevertheless, if you want there is a chapter on "Knight's Forensic Pathology" book.
Thank you Dr. Martinez-Garcia, a very interesting article published in "Cuad. Med Forense nº 51. Jan 2008".
But I belive that are substantial diferences between permanent sequels as a result of the injuries suffered by an accident by electricity of high tension and postmortem amputation due to high tension electrocution.
As you can see in the attached photo, the right hand was amputated associated with deep burns in the neck, all postmortem injuries.