Photocatalytic hydrogen production through splitting of water is a process that converts solar energy into chemical energy by means of a suitable photocatalyst. For this purpose, one can use different catalysts such as TiO2 and ZnO-based photocatalysts. Although this reaction thermodynamically is unspontaneous, the applied light provides energy for this reaction. In electrical splitting of water, electricity provides energy for this conversion. These thermodynamically unspontaneous reactions are very similar to photosynthesis reactions in plants, in which CO2 molecules converts to organic compounds. In addition, by using photocatalytic processes, one can convert CO2 gas to value-added fuels such as methanol. This is an unspontaneous reaction also. For more information, please refer to the attached review papers.