Most probably it would be quite difficult. Cobalt forms a variety of rather stable chemical compounds with water, ammonia and chlorine, so it would be difficult to dislodge it from these compounds using Prussia blue. Different chemistry from the of of Caesium.
Yes! After chemical modification of the sorbent. Please read the paper by Chmielewska and Stachurska: J Radioanal Nucl Chem (2016) 307:1295–1301 DOI 10.1007/s10967-015-4291-2