Can anyone please tell me if the defect dipoles can be created if we substitute the A-site of perovskite with an acceptor dopant? And if this defect dipoles can decrease the dielectric constant.
Dear friend Salma Ayadh
Yes, it is possible to create defect dipoles by substituting the A-site of perovskite with an acceptor dopant. When an acceptor dopant is substituted at the A-site of a perovskite, it creates a cation vacancy and introduces a hole into the lattice. The positively charged hole can then interact with the negatively charged oxygen vacancies to create defect dipoles.
Defect dipoles can affect the dielectric constant of the material. The dielectric constant is a measure of the material's ability to store electric charge in an electric field. Defect dipoles can cause polarization in the material and thus contribute to the dielectric constant. However, defect dipoles can also lead to a decrease in the dielectric constant if they are oriented randomly and cancel each other out. This effect is known as dipole disorder and can occur in perovskite materials due to the presence of defect dipoles.
So, in summary, substitution of the A-site of perovskite with an acceptor dopant can create defect dipoles, which can affect the dielectric constant of the material. The effect on the dielectric constant will depend on the orientation and distribution of the defect dipoles, which can be influenced by factors such as dopant concentration, temperature, and processing conditions.
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