Cinchona and prolinol ether based catalysts are well known for the Michael addition of unsaturated carbonyl compounds. There are many metal catalysts but I am looking for some other organocatalysts used for the same.
There are examples with the use of a catalytic amount of proline together with 2,5-trans-dimethylpiperazine as stoichiometric additive. Hanessian, S.; Pham, V. Org. Lett., 2000, 2, 2975-2978