Most of the literatures report on Ag-Cu heterometallic clusters typically involve clusters containing metal in the 0 oxidation state. However, we have synthesized a cluster consisting entirely of Ag(I) and Cu(I). I'm wondering if there are similar examples?
My recommendation is to search the CSD and extract the informations from the crystal structures. If you find suitable papers, they may contain XANES or other appropriate diffraction technique which confirms oxidation state and novelty of your compound.
Hi!
d10-d10 interactions are nifty and do exist. A quick search brings up this review on the topic: https://pubs.rsc.org/en/content/articlelanding/2011/cs/c0cs00102c/unauth
Looks like that and a forward search would be a good place to start to see what's out in the literature.
Good luck!
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