The absolute intensity can be affected by many factors. You can start by sorting out instrumental effects. For example - did you measure both samples mounted side by side or was it two separate experiments?
Then, in addition, you also need to consider sample-related effects. XPS signal is directly proportional to the number of atoms in the probed volume. After doping you may simply "dilute" the Ti concentration compared to the original sample.
The absolute intensity can be affected by many factors. You can start by sorting out instrumental effects. For example - did you measure both samples mounted side by side or was it two separate experiments?
Then, in addition, you also need to consider sample-related effects. XPS signal is directly proportional to the number of atoms in the probed volume. After doping you may simply "dilute" the Ti concentration compared to the original sample.