In Fe doped BaTiO3 ceramics, both crystalline size and grain size will increase with increasing Fe concentration.
Can anyone explian ?
Do you observe (111) twins in BaTiO3 grains? They could form on doping with 3+ cations and trigger exaggerated grain growth. Check you microstructures for twins.
It could be that the presence of iron (Fe3+, Fe2+) promotes the formation of a second phase which is formed in the matrix of BaTiO3.
It may be an accelerated diffusion caused by doping. lower activation energy?
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