Dielectric properties of materials can vary with frequency due to various mechanisms. The nature of the dielectric material and the frequency of the applied electric field are both factors that influence this variation. To understand the variation of dielectric constant with frequency, we must consider different polarisation mechanisms that occur at different frequency ranges: electronic, atomic, and orientation polarization.
Electronic Polarisation occurs at very high frequencies (UV, visible light). The electric field displaces the electron cloud with respect to the nucleus in an atom, leading to a polarized atom.
Atomic or Ionic Polarisation: This occurs at lower frequencies (infrared). It involves the displacement of the positive and negative ions in relation to each other within the atom or molecule.
Orientation Polarisation: This occurs at even lower frequencies (radio waves) and involves reorientating entire molecules - particularly polar ones (i.e., have a permanent dipole moment), such as water.
As the frequency increases, each type of polarization mechanism eventually can't respond quickly enough - their response to the changing electric field lags behind. This means they can't contribute to the total polarization of the material, which effectively reduces the dielectric constant.
Maxwell's equations provide a fundamental description of electromagnetism, of which dielectrics are a part. Maxwell's equations can help describe how the electric field propagates through and interacts with these materials in the context of dielectric materials. Specifically, the displacement field (D) is defined by Maxwell as D = εE, where ε is the permittivity (or dielectric constant), and E is the electric field. This equation tells us how an electric field will interact with a dielectric material (since permittivity is a material property).
The frequency-dependence of the dielectric constant is sometimes included by making the permittivity a complex quantity, ε = ε' - iε'', where ε' is the 'real' part (related to energy storage), and ε'' is the 'imaginary' part (related to energy loss, or dissipation). This complex permittivity can then be included in Maxwell's equations to study the behaviour of electromagnetic waves in the material, including phenomena like dispersion and absorption.
In addition to Maxwell's equations, the theory of dielectric dispersion, often attributed to Debye, can be used to understand the frequency dependence of the dielectric constant. Debye's theory describes how different polarization mechanisms respond to changing electric fields with different speeds, leading to the observed frequency dependence.