I am currently working in material synthesis for PEC water splitting application.

Could someone please give me some detailed explanation why do current density of in the two-electrode system (full cell) is sometimes lower as compared to three-electrode (half-celf)?

I have found some papers (see attached) also observed similar phenomena but without explanation.

WE: Semiconductor

CE: Pt mesh

Thank you in advance for your help

In case of three-electrode configuration, Ag/AgCl was used as reference.

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