In general, the steroidal alkaloids represent an important class of alkaloids that essentially afford a close structural relationship to sterols i.e., they contain a perhydro-1, 2-cyclopentanophenanthrene nucleus. Interestingly, these group of alkaloids invariably occur in the plant kingdom as glycosidal combination with carbohydrate moieties.
The steroidal alkaloids may be broadly classified into two major groups, namely:
(a) Solanum Alkaloids, and
(b) Veratrum Alkaloids.