Initially treat PDMS in a low power plasma @30 sec. for surface modification and better adhesion. Better try to deposit by Sputtering with Argon plasma @ very low gas flow rate. Cr/Au has no problem, also you can use Nickel , Ni-chrome.
If you can help me in expanding the abbreviation of your material PDMS, as I am not aware of it. This will help me answering your question conveniently.