Vidisha, it is difficult to tell for certain which size is better without experimental data. Depends on a catalyst. In some cases it is smallest size, in some cases certain size gives best results. Just tell which catalyst you use.
If you are talking about producing hydrogen by catalytic decomposition of methane then catalyst reduced to particular mesh size is more helpful. It depends upon the type of catalyst one is using. For example if Fe-Ni or Fe-Mo supported over silica is used as a catalyst then 100 mesh size is preferred.