One detailed presentation of the ADM formalism may be found here: http://wwwteor.mi.infn.it/~molinari/TESI/Danieli_tesi.pdf; another is here: http://philsci-archive.pitt.edu/11446/1/Giulini.pdf
but, by itself, the formalism doesn't have anything to do with loop quantum gravity.
The ADM formalism is classical.
How to recover general relativity from loop quantum gravity is, still, an open problem.
A review of the issues involving the constraints may be found here: Article Critical Overview of Loops and Foams