It's silly, but I want to make sure that I am not changing the pH and ORP when I dilute my solution
Not likely.
No, but be sure of the pH of your D.W. and it is stable and clean before using it.
Why not try and see? It is a simple experiment. An analytical chemistry lab should have a pH meter.
Not sure about ORP, but pH will definitely change. As you dilute acidic solution with water, the concentration of H+ in the final medium decreases, pH= -log[H+] so then pH will increase.
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