say, when we take a simple titration of any compound to induce some change and study the change what we can see the change if it is faster change in the optical parameter or change in absorption or energy change or when we do its electro chemical analysis the changed species will be faster response as its electron transfer, what will be faster ? or both the methodologies will be different in kinetics due to different technical aspects and parameters? optical corresponds to the technique spectrophotometric methods . and more elaboratively from which technique we can get better electron transfer kinetics or the accurate degree of minimal observable change.

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