Actually my doubt is regarding STIFF SYSTEMS. What is the speciality that ode15s possess which ode45 doesn't have so as to use the former one to deal with stiff systems? Is it merely the difference between explicit scheme and implicit scheme which makes them different? Suppose I have an example for the so called 'STIFF SYSTEMS. If I use both solvers ode45 and ode15s to solve it, definitely the system being stiff ode45 either takes long time to give a solution or may not give also. Other than the computation time, can I track some other parameter whose performance given by both the solvers be compared ,which tells me exactly what this stiff property means?