What is the value should I subtract from the Eonset of Cyclic Voltametry (CV) to get the HOMO and LUMO value?

05 November 2017 1 6K Report

HOMO=-e[Eox-onset - X];

LUMO=-e[Ered-onset-X]

Did anyone have the list for X values?

From several papers, I found that the X values for ferrocence are sometime 3.8, 4.4, 4.3; tetrabutylammonium percholate is like 4.8-4.9.

What if I am using NaHCO3 as the electrolyte during CV?

Mati Ur Rahman

4.8

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