What is the reason for shifting of peaks in the glancing angle thin film(glass substrate) XRD?

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Imad Disher

Generally, the shift of the peaks in XRD can be attributed to:

1- The change of the d-spacing of the investigated system, this may attributed to many reasons including the effect of dopant, strain, surface (for nanomaterials

Kshetramohan Dehury

How the effect of the dopant and strain attributed to change of d spacing in the investigated system?

Please refer to any textbook on XRD, Elements of X-Ray Diffraction by Cullity, B. D is a good one.

Also, you can find details on previous RG answers:

https://www.researchgate.net/post/Any_suggestions_for_why_the_XRD_peak_shifts

https://www.researchgate.net/post/When_XRD_analyzed_what_does_it_mean_when_a_shifted_peak_is_either_left_hand_or_right_hand2

https://www.researchgate.net/post/What_is_the_reason_of_peak_shifting_in_XRD_towards_higher_angle_side_after_the_sample_has_been_irradiated