If the ray of light (e.g. sunlight) is going through the atom, atom will absorb specific wavelength of light. Then, we see the unabsorbed wavelength part of light. For example, if atom absorbs red, we see blue (or green maybe?). But I learned that excited atom deexcites almost immediately. So doesn't it have to detect white light because the lights combine? Some people said that it is because of random direction of emission but I cannot understand. If it is so, when the distance between me and an atom is r, and the area of my eye is A, the probability of observing white light should be A / 4pi*r^2, isn't it?