What is the minimum energy required to change the orbital angular momentum or orbital energy?

I would like to explain my question with the following illustrative situation. In general, when we apply external perturbation such pressure, and temperature to the crystalline materials, the atomic orbital energy levels are modified. In precise, how much minimum required temperature or pressure is needed to get the significant changes in orbital?

Your valuable explanation, suggestion, and guidance will be very useful to our research works. Thank you very much in advance.

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