Various experimental and theoretical findings suggests the effect of next-nearest-neighbor (NNN) hopping amplitude t' on the physical properties of the cuprates. The magnitude of t' is found to be material dependent and is different for different materials. moreover the sign of t' is different for electron and hole doped cuprates.But what is the range of magnitude of t'? More specifically what regime of t' is associated with high Tc cuprates? What is the maximum values of t' in both electron and hole doped material respectively? To, which compound they are associated with?