Dear All,
For understanding the phase immiscibility, I have searched for the related amounts of each content. I have found some studies indicating the limit of B2O3 as 25 mol%. However, I have encountered some researches specifying it as 40 mol%. Therefore, what is the limit for B2O3 addition?
Many thanks.
Dear Recep,
as a synthetic inorganic chemist I'm certainly not an expert in glass technology. However, I can recommend to you a few relevant literature references which could help answering your interesting technical question. For example, please have a look at the following potentially useful articles:
Immiscibility in the TeO2-B2O3 system
Article Immiscibility in the TeO2-B2O3 system
Unfortunately this article has not yet been posted by the authors as public full text on RG. Perhaps you can access it through your institution. Yet another relevant article is the following:
Unusual Immiscibility Structures in Tellurite Glasses
Article Unusual Immiscibility Structures in Tellurite Glasses
The first author of this article has an RG profile. Thus it should be possible to request the full text of the paper directly from her.
Also please see:
Phase equilibrium, glass-forming, properties and structure of glasses in the TeO2-B2O3 system
Article Phase equilibrium, glass-forming, properties and structure o...
Good luck with your work!
Dear Frank T. Edelmann
I appreciate your kind interest and response. I will certainly have a look at them for understanding immiscibility. As usual, you made your best for helping young researchers, thanks a lot!
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