Dear Haider Umran, generally speaking the higher the MW, thicker is the film and vice-versa. This is because the spreading is difficult because of the viscosity. Other thing to consider that the high viscosity also hinder the ease of film drying. My Regards
Generally the thickness of the films increases with the molecular chain of the polymers. Also the length of the chains plays an important role because the diffusion of the polymers is slowed down by the tangles of the chains.