Selectivity is the quality of a response that can be achieved without interference for any other substance. Sensitivity is how low can you detect the substance of interest. The best analytical method offers the highest sensitivity and highest selectivity. It is desirable to have both properties as high as possible; it depends on the circumstances of the analysis if one of the properties can be sacrificed for the other.
selectivity, how the methods detection gave response without interference, sensitivity, mean the lowest concentration that the methods of detection gave response either accurate or not accurate.